Home Interior Upgrades Surrey

Home Interior Upgrades Surrey

Home improvement ideas Surrey

They listen to your needs, preferences, and dreams, turning them into reality with precision and creativity. However, over time, they've shown to degrade under certain conditions, leading to leaks, water damage, and costly repairs. It's clear that Canyon Property Projects Ltd doesn't just renovate homes; they reinvent them, ensuring every project reflects the homeowner's personality and meets their needs. Learn more about Home Interior Upgrades Surrey here They communicate proactively, keeping you informed every step of the way and ensuring there are no surprises. From solar panels to smart thermostats and LED lighting, they're all about making your home more environmentally friendly and economical to run.
With Canyon Property Projects Ltd., you're not just getting a contractor; you're gaining a partner invested in the lasting quality and satisfaction of your home improvement project. Bathroom renovation With them, your home transformation is in expert hands. They're transparent about timelines and costs, so you're never in the dark. Residential remodeling They're all about flexibility and adaptability, ensuring that the final outcome not only meets but exceeds your expectations.
They listen closely to your needs and dreams, using them as a foundation for the design process. We source the best, from high-grade lumber for your decking to premium tiles for your bathroom renovation. With Canyon Property Projects Ltd., you can rest assured that your home is in skilled hands. Learn more about Canyon Property Projects Ltd. here. Their designs reflect a deep understanding of modern living, blending smart technology seamlessly with elegant, sustainable materials to create environments that are both beautiful and intelligent.
This dynamic market can significantly influence the types and extents of renovations that'll resonate most with potential buyers or enhance your property's value. For homeowners, how will your needs evolve? This not only helps in conserving energy but also significantly lowers your utility bills. Flooring installation The next step involves finalizing the design and project details.

You'll be amazed at how spaces are completely reimagined, turning outdated rooms into modern havens. This is crucial because nothing slows down a project like red tape. The market also favors well-maintained outdoor spaces, hinting at the importance of landscaping and exterior improvements.

Closet renovations

  1. Basement waterproofing
  2. Entertainment room renovation
  3. Garage conversion
  4. Eco-friendly renovations
  5. Custom cabinetry
  6. Soundproofing renovation
  7. Crown molding installation
  8. Soaking tub installation
  9. Surrey heritage home restoration
  10. Window replacement
  11. Smart home upgrades
  12. Baseboard and trim renovation
  13. Luxury home remodeling Surrey
  14. Full-service renovation Surrey
  15. Vanity replacement
You're not just getting a renovation; you're investing in a project that's mindful of its environmental impact.

Moving from a broad overview of services, let's focus on how kitchen renovation solutions can dramatically enhance your home's value and functionality. Whether you're curious about their design philosophy, eager to browse through their before and after gallery, or interested in learning how they integrate sustainability into every project, Canyon Property Projects Ltd offers a comprehensive approach to modernizing your home. It's this dedication to your satisfaction that sets Canyon Property Projects Ltd. apart, making them a trusted choice for your home improvement needs.

They understand that the beauty of any renovation or construction project lies in both its appearance and its durability. You won't just be investing in your property; you're investing in countless memories to come. Once you give the green light, their team swings into action, meticulously planning and scheduling each phase to minimize disruptions to your daily life. Home theater installation

With a keen eye for detail, they ensure that every project, whether it's a state-of-the-art kitchen, a luxurious bathroom, or an entire home makeover, exceeds their clients' expectations.

Trusted renovation contractors Surrey

  • Soundproofing renovation
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  • Full-service renovation Surrey
  • Vanity replacement
  • Drywall installation and repair
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  • Local home renovators Surrey
  • Living room renovation
  • Porch renovation
  • Walk-in shower installation
  • Painting and wall finishes
It's about creating a harmonious connection between your home and its surroundings.

Renovation contractors

  1. Full-service renovation Surrey
  2. Vanity replacement
  3. Drywall installation and repair
  4. Green home remodeling
  5. Accessible home design
  6. Project management
  7. Financing options for renovation
  8. Local home renovators Surrey
  9. Living room renovation
  10. Porch renovation
  11. Walk-in shower installation
  12. Painting and wall finishes
  13. Home office renovation
  14. Plumbing upgrades
  15. Built-in storage solutions
Their attention to detail and commitment to excellence is unmatched.' This sentiment is echoed by a homeowner, who says, 'They turned our vision into reality, improving our living space in ways we didn't think possible.

Citations and other links

House Renovation Services Home Interior Upgrades Surrey

Think of state-of-the-art appliances that transform cooking from a chore into a joy, and custom cabinets that fit your kitchen's unique dimensions like a glove, optimizing storage without compromising on aesthetics. We also emphasize sustainability, selecting materials and appliances that are both eco-friendly and durable. Whether you're looking to breathe new life into your living space or embark on a more ambitious construction project, their streamlined process and dedication to excellence promise to turn your vision into reality. You've got to dig deep into what you want your property to look and feel like, considering both its aesthetic appeal and functionality. From the initial consultation to the final touches, they're there to ensure your vision becomes a reality, listening closely to your ideas and providing expert advice to enhance the outcome.

Focusing on quality and efficiency, Canyon Property Projects ensures your home improvement is completed to the highest standards, on time and within budget. You'll notice the difference in the fine finishes, the precision in the construction, and the meticulous attention to detail. Moreover, they're always up-to-date with the latest trends and technologies, ensuring your home isn't just stylish but also smart and sustainable. Beyond customizing your space, Canyon Property Projects Ltd.

Entryway remodeling

  1. Drywall installation and repair
  2. Green home remodeling
  3. Accessible home design
  4. Project management
  5. Financing options for renovation
  6. Local home renovators Surrey
  7. Living room renovation
  8. Porch renovation
  9. Walk-in shower installation
  10. Painting and wall finishes
  11. Home office renovation
  12. Plumbing upgrades
  13. Built-in storage solutions
  14. Experienced renovation team Surrey
  15. Affordable home remodeling Surrey
  16. Exterior home renovation
  17. Home gym remodeling
  18. Home insulation upgrades
also ensures that each project meets exceptional quality standards.

Home improvement ideas Surrey

  • Laminate flooring installation
  • Whole house renovation
  • Backsplash installation
  • Foundation repair
  • Home remodeling consultation
  • Attic renovation
  • Home addition services
  • Bathroom tile renovation
  • Residential remodeling
  • Permit and code compliance
  • Basement waterproofing
  • Entertainment room renovation
  • Garage conversion
  • Eco-friendly renovations
  • Custom cabinetry
  • Soundproofing renovation
  • Crown molding installation
  • Soaking tub installation
  • Surrey heritage home restoration
  • Window replacement


They don't just stop at aesthetics; functionality is key in their designs. With a keen eye for detail and a commitment to quality, they've transformed mundane spaces into stunning, functional homes. You'll find they use only top-grade materials that guarantee durability and aesthetics. They're constantly pushing the envelope, incorporating the latest techniques and materials to ensure your home not only looks fantastic but is also built to last.

From complex renovations that breathe new life into old homes to cutting-edge designs that transform your living space, they've got the skills to make your vision a reality. Each before and after photo pairs tell a story of potential realized. You'll appreciate their attention to detail, from the choice of soothing color palettes to the installation of energy-efficient lighting that enhances the ambiance of your space. You can't help but be impressed by the visual proof of their expertise.

House Renovation Services Home Interior Upgrades Surrey
Kitchen And Bath Renovation Home Interior Upgrades Surrey

Kitchen And Bath Renovation Home Interior Upgrades Surrey

You'll notice a significant decrease in your energy consumption, leading to lower utility bills and a more comfortable living environment. This approach not only enhances the aesthetic appeal of your home but also increases its value and longevity. That's why they offer customized solutions that mirror your lifestyle and meet your specific needs. This holistic approach is what sets them apart in the Home Interior Upgrades Surrey home improvement scene.
They don't just transform houses; they reimagine what your living space can be, from the ground up. Every Home Interior Upgrades Surrey homeowner's needs and tastes are unique, demanding tailored design solutions to create the perfect living space. We're dedicated to delivering not just quality work, but also peace of mind, knowing your project will be completed on schedule. Foundation repair
By identifying key areas for improvement, such as modernizing kitchens and bathrooms, upgrading heating and cooling systems, and enhancing outdoor living spaces, you can expect a considerable return on investment (ROI). Home improvement ideas Surrey Read more about Home Interior Upgrades Surrey here Their team specializes in both minor upgrades and major renovations, tailoring each project to fit your specific needs and budget.

Entryway remodeling

  1. Smart home upgrades
  2. Baseboard and trim renovation
  3. Luxury home remodeling Surrey
  4. Full-service renovation Surrey
  5. Vanity replacement
  6. Drywall installation and repair
  7. Green home remodeling
  8. Accessible home design
  9. Project management
  10. Financing options for renovation
  11. Local home renovators Surrey
  12. Living room renovation
  13. Porch renovation
  14. Walk-in shower installation
  15. Painting and wall finishes
What sets Canyon Property Projects Ltd apart is their commitment to making your dream home a reality, tailored precisely to what you've envisioned.
You'll find them catching potential issues before they become problems, ensuring that the work is on track and up to par. Backsplash installation Countertop installation After completion, they'll walk you through the project, showing you the ins and outs of what's been done. They're not just talking the talk; they're walking the walk by prioritizing renewable resources and energy-efficient solutions that benefit both you and the planet.

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By prioritizing sustainable practices, Canyon Property Projects Ltd. not only impacts the environment positively but also earns rave reviews from clients who've seen their homes transformed. They take your vision and turn it into reality, making sure every aspect of the project reflects your personal style while adding value to your home. You'll find that their approach isn't just about making changes to your home; it's about transforming your living space with meticulous attention to detail and a deep respect for your vision. At the heart of their success is a commitment to quality and customer satisfaction, setting them apart in a crowded market.

Backsplash installation

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  2. Plumbing upgrades
  3. Built-in storage solutions
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  6. Exterior home renovation
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  15. Basement finishing
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This not only helps the environment but also reduces your utility bills.

They want to make sure you're not just satisfied, but delighted.

Closet renovations

  • Home gym remodeling
  • Home insulation upgrades
  • Exterior siding replacement
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  • Entryway remodeling
They're not just about aesthetics; they prioritize functionality, ensuring every space is optimized to meet your needs. Whether you're looking to create a spa-like retreat or a sleek, modern space, the right enhancements can transform your bathroom into a sanctuary. You'll find that they cleverly integrate storage solutions in places you'd never think to look, making clutter a thing of the past.

If you've been considering giving your home a facelift or a complete overhaul, you'll want to explore how Canyon's expanded services and client-centric approach could make your vision a reality. If you're aiming to reduce your carbon footprint or incorporate smart home features, Canyon Property Projects Ltd. is ready to bring those visions to life. Custom vanity areas with ample storage and lighting can make getting ready in the morning a pleasure rather than a chore. They're committed to enhancing your home's functionality and efficiency, incorporating the latest technologies and sustainable materials wherever possible.

They'll help you navigate the benefits of hardwood versus engineered flooring, the ins and outs of various countertop materials, and the best appliances for your lifestyle. Whether you're aiming to enhance a property's value before a sale or you're looking to customize your home to better fit your lifestyle, they've got you covered. Imagine sleek granite countertops that not only dazzle the eye but also withstand the test of time and culinary challenges. They know that no two projects are the same, which is why they've ditched the one-size-fits-all approach.

Home Interior Upgrades Surrey Landscaping And Design
Condo Renovation Home Interior Upgrades Surrey
Condo Renovation Home Interior Upgrades Surrey

Understanding the comprehensive services offered by Canyon Property Projects Ltd is just the beginning; now, let's explore how they tailor each project to meet your unique needs and desires. Embarking on a home improvement journey can often feel like navigating through a dense forest, full of unknowns and potential pitfalls. By implementing precise planning and using materials efficiently, they significantly decrease the amount of waste sent to landfills. Their work is truly transformative.'Another testimonial highlights the company's professionalism and customer service: 'From start to finish, the communication was clear, and the project was completed on time and within budget.

They're equally diligent about the functionality and durability of their work. They're not just about making your space look good; they're dedicated to ensuring the whole process is stress-free for you. Trusted renovation contractors Surrey Many homeowners are unaware that the plumbing in their houses may include Poly B pipes, a material known for its high failure rate.

Entryway remodeling

  1. House remodeling experts
  2. Interior painting
  3. Laminate flooring installation
  4. Bathroom tile renovation
  5. Residential remodeling
  6. Permit and code compliance
  7. Basement waterproofing
  8. Entertainment room renovation
  9. Garage conversion
  10. Eco-friendly renovations
  11. Custom cabinetry
  12. Soundproofing renovation
  13. Crown molding installation
  14. Soaking tub installation
  15. Surrey heritage home restoration
  16. Window replacement
  17. Smart home upgrades
  18. Baseboard and trim renovation
  19. Luxury home remodeling Surrey


From the initial consultation, you're guided through every step. Whether it's installing solar panels, rainwater harvesting systems, or incorporating advanced insulation techniques, they're committed to making your space as energy-efficient as possible. Embracing sustainability, Canyon Property Projects Ltd. integrates eco-friendly materials and practices into your home improvement projects, ensuring a greener future.

Their approach to space transformation also focuses on enhancing natural light and optimizing energy efficiency, ensuring your home isn't only beautiful but also sustainable and cost-effective to run. Whether it's through sustainable building practices that promise a greener future, personalized renovations that cater uniquely to the homeowner's lifestyle, or comprehensive quality control that ensures every project is nothing short of perfection, Canyon Property Projects Ltd. is leading the way. Renovation contractors Canyon Property stands out for its dedication to customer satisfaction.

Complete House Revamp Home Interior Upgrades Surrey

This foresight allows them to adjust plans swiftly, ensuring minimal disruption to your operations. They don't just look at the immediate issue; they consider the long-term implications of their solutions to ensure you won't face similar problems down the line. For those dreaming of a home that perfectly reflects their unique style and lifestyle, Canyon Property Projects Ltd. offers bespoke home transformations. So, investing in your property's curb appeal isn't just about aesthetics; it's a strategic move that pays off in both satisfaction and financial returns. Their personalized approach means you're involved every step of the way.
That's what you get when you work with their team. Whether it's a kitchen remodel, a bathroom renovation, or an entire home transformation, Canyon Property Projects Ltd crafts each space with passion and precision. They're usually gray, sometimes marked with 'PB2110'. Imagine your drab kitchen, with its worn-out countertops and old cabinets, transformed into a sleek, functional space where you love to spend time.
From installing energy-efficient windows to setting up smart home systems that allow you to control your heating, lighting, and security remotely, they're all about merging convenience with sustainability.

Home improvement ideas Surrey

  • Closet renovations
  • Hardwood floor refinishing
  • Bathroom renovation
  • Countertop installation
  • Home theater installation
  • Renovation contractors
  • Tile installation services
  • Whole house renovation
  • Backsplash installation
  • Foundation repair
  • Home remodeling consultation
  • Attic renovation
  • Home addition services
  • Bathroom tile renovation
  • Residential remodeling
  • Permit and code compliance
You're not left in the dark; instead, you're part of the journey, from conception to completion. When you dive into the testimonials, you'll notice a recurring theme of satisfaction and gratitude. Whether you're updating your home to better suit your lifestyle or preparing to sell, their expertise is at your disposal.
Imagine stepping through your living room straight into a beautifully integrated outdoor patio, where the transition feels as natural as walking from your kitchen to your dining room. Their team of experts doesn't just think about the aesthetics; they consider the functionality of your space, ensuring every square inch serves a purpose. From initial design consultation to the final touches, their team is with you every step of the way. Just as Canyon Property Projects Ltd transforms kitchens into culinary masterpieces, they also specialize in turning bathrooms into bespoke retreats tailored to your personal taste and needs.

Explore Home Interior Upgrades Surrey here
Complete House Revamp Home Interior Upgrades Surrey
Polybutylene
Names
Other names
polybutene-1, poly(1-butene), PB-1
Identifiers
ChemSpider
  • none
ECHA InfoCard 100.111.056 Edit this at Wikidata
Properties
(C4H8)n
Density 0.95 g/cm3[1]
Melting point 135 °C (275 °F; 408 K)[1]
Related compounds
Related compounds
1-butene (monomer)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Polybutylene (polybutene-1, poly(1-butene), PB-1) is a polyolefin or saturated polymer with the chemical formula (CH2CH(Et))n. Not be confused with polybutene, PB-1 is mainly used in piping.[2]

Production

[edit]

Polybutylene is produced by polymerisation of 1-butene using supported Ziegler–Natta catalysts.

Catalysts

[edit]

Isotactic PB-1 is produced commercially using two types of heterogeneous Ziegler–Natta catalysts.[3] The first type of catalyst contains two components, a solid pre-catalyst, the δ-crystalline form of TiCl3, and solution of an organoaluminum cocatalyst, such as Al(C2H5)3. The second type of pre-catalyst is supported. The active ingredient in the catalyst is TiCl4 and the support is microcrystalline MgCl2. These catalysts also contain special modifiers, organic compounds belonging to the classes of esters or ethers. The pre-catalysts are activated by combinations of organoaluminum compounds and other types of organic or organometallic modifiers. Two most important technological advantages of the supported catalysts are high productivity and a high fraction of the crystalline isotactic polymer they produce at 70–80 °C under standard polymerization conditions.[4][5][6]

Characteristics

[edit]

PB-1 is a high molecular weight, linear, isotactic, and semi-crystalline polymer. PB-1 combines typical characteristics of conventional polyolefins with certain properties of technical polymers.

PB-1, when applied as a pure or reinforced resin, can replace materials like metal, rubber and engineering polymers. It is also used synergistically as a blend element to modify the characteristics of other polyolefins like polypropylene and polyethylene. Because of its specific properties it is mainly used in pressure piping, flexible packaging, water heaters, compounding and hot melt adhesives.

Heated up to 190 °C and above, PB-1 can easily be compression moulded, injection moulded, blown to hollow parts, extruded, and welded. It does not tend to crack due to stress.[dubiousdiscuss] Because of its crystalline structure and high molecular weight, PB-1 has good resistance to hydrostatic pressure, showing very low creep even at elevated temperatures.[7] It is flexible, resists impact well and has good elastic recovery.[3][8]

Isotactic polybutylene crystallizes in three different forms. Crystallization from solution yields form-III with the melting point of 106.5 °C. Cooling from the melt results in the form II which has melting point of 124 °C and density of 0.89 g/cm3. At room temperature, it spontaneously converts into the form-I with the melting point of 135 °C and density of 0.95 g/cm3.[1]

PB-1 generally resists chemicals such as detergents, oils, fats, acids, bases, alcohol, ketones, aliphatic hydrocarbons and hot polar solutions (including water).[3] It shows lower resistance to aromatic and chlorinated hydrocarbons as well as oxidising acids than other polymers such as polysulfone and polyamide 6/6.[7] Additional features include excellent wet abrasion resistance, easy melt flowability (shear thinning), and good dispersion of fillers. It is compatible with polypropylene, ethylene propylene rubbers, and thermoplastic elastomers.

Some properties:[7]

Application areas

[edit]

Piping systems

[edit]

The main use of PB-1 is in flexible pressure piping systems for hot and cold drinking water distribution, pre-insulated district heating networks and surface heating and cooling systems. ISO 15876 defines the performance requirements of PB-1 piping systems.[9] PB-1's most notable characteristics are weldability, temperature resistance, flexibility and high hydrostatic pressure resistance. The material can be classified PB 125 with a minimum required strength (MRS) of 12.5 MPa. Other features include low noise transmission, low linear thermal expansion, no corrosion and calcification.

PB-1 piping systems are no longer being sold in North America (see "Class action lawsuits and removal from building code approved usage", below). The overall market share in Europe and Asia is rather small but PB-1 piping systems have shown a steady growth in recent years. In certain domestic markets, e.g. Kuwait, the United Kingdom, Korea and Spain, PB-1 piping systems have a strong position.[8]

Plastic packaging

[edit]

Several PB-1 grades are commercially available for various applications and conversion technologies (blown film, cast film, extrusion coating). There are two main fields of application:

  • Peelable easy-to-open packaging where PB-1 is used as blend component predominantly in polyethylene to tailor peel strength and peel quality, mainly in alimentary consumer packaging and medical packaging.
  • Lowering seal initiation temperature (SIT) of high speed packaging polypropylene based films. Blending PB-1 into polypropylene, heat sealing temperatures as low as 65 °C can be achieved, maintaining a broad sealing window and good optical film properties.

Hot melt adhesives

[edit]

PB-1 is compatible with a wide range of tackifier resins. It offers high cohesive and adhesive strength and helps tailoring the "open time" of the adhesive (up to 30 minutes) because of its slow crystallisation kinetics. It improves the thermal stability and the viscosity of the adhesive.[10]

Compounding and masterbatches

[edit]

PB-1 accepts very high filler loadings in excess of 70%. In combination with its low melting point it can be employed in halogen-free flame retardant composites or as masterbatch carrier for thermo-sensitive pigments. PB-1 disperses easily in other polyolefins, and at low concentration, acts as processing aid reducing torque and/or increasing throughput.

Thermal insulation

[edit]

PB-1 can be foamed.[11] The use of PB-1 foam as thermal insulation is of great advantage for district heating pipes, since the number of materials in the sandwich structure is reduced to one, facilitating its recycling.[12]

Other applications

[edit]

Other applications include domestic water heaters, electrical insulation, compression packaging, wire and cable, shoe soles, and polyolefin modification (thermal bonding, enhancing softness and flexibility of rigid compounds, increasing temperature resistance and compression set of soft compounds).

Environmental longevity

[edit]

Plumbing and heating systems made from PB-1 have been used in Europe and Asia for more than 30 years. First reference projects in district heating and floor heating systems in Germany and Austria from the early 1970s are still in operation today.[8]

One example is the installation of PB-1 pipes in the Vienna Geothermal Project (1974) where aggressive geothermal water is distributed at a service temperature of 54 °C and 10 bar pressure. Other pipe materials in the same installation failed or corroded and had been replaced in the meantime.[8]

International standards set minimum performance requirements for pipes made from PB-1 used in hot water applications. Standardized extrapolation methods predict lifetimes in excess of 50 years at 70 °C and 10 bar.[8]

Class action lawsuits and removal from building code approved usage

[edit]

Polybutylene plumbing was used in several million homes built in the United States from around 1978 to 1997. Problems with leaks and broken pipes led to a class action lawsuit, Cox v. Shell Oil, that was settled for $1 billion.[13][14] The leaks were associated with degradation of polybutylene exposed to chlorinated water.[15]

Polybutylene water pipes are no longer accepted by the United States building codes and have been the subject[16] of class action lawsuits in both Canada and the U.S.[17][18] The National Plumbing Code of Canada 1995 listed polybutylene piping as acceptable for use with the exception of recirculation plumbing. The piping was removed from the acceptable for use list in the 2005 issue of the standard.[19]

In Australia in March 2023, the Department of Mines, Industry Regulation and Safety reported that Australian homes built in 2019-2020 that had used a certain brand of polybutylene piping, had become the subject of an enquiry due to the significance of water leaks reported.[20][21]

There is evidence to suggest that the presence of chlorine and chloramine compounds in municipal water (often deliberately added to retard bacterial growth) will cause deterioration of the internal chemical structure of polybutylene piping and the associated acetal fittings.[22] The reaction with chlorinated water appears to be greatly accelerated by tensile stress, and is most often observed in material under highest mechanical stress such as at fittings, sharp bends, and kinks. Localized stress whitening of the material generally accompanies and precedes decomposition of the polymer. In extreme cases, this stress-activated chemical "corrosion" can lead to perforation and leakage within a few years, but it also may not fail for decades. Fittings with a soft compression seal can give adequate service life.[further explanation needed]

Because the chemical reaction of the water with the pipe occurs inside the pipe, it is often difficult to assess the extent of deterioration. The problem can cause both slow leaks and pipe bursting without any previous warning indication. The only long-term solution is to completely replace the polybutylene plumbing throughout the entire building.[23]

See also

[edit]

References

[edit]
  1. ^ a b c Mark Alger, Mark S. M. Alger (1997). Polymer science dictionary. Springer. p. 398. ISBN 978-0-412-60870-4.
  2. ^ Whiteley, Kenneth S.; Heggs, T. Geoffrey; Koch, Hartmut; Mawer, Ralph L.; Immel, Wolfgang (2000). "Polyolefins". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a21_487. ISBN 978-3527306732.
  3. ^ a b c d Charles A. Harper (2006). Handbook of plastics technologies: the complete guide to properties and performance. McGraw-Hill Professional. p. 17. ISBN 978-0-07-146068-2.
  4. ^ Hwo, Charles C.; Watkins, Larry K. Laminated film with improved tear strength, European Patent Application EP0459742, Publication date 12/04/1991
  5. ^ Boo-Deuk Kim et al. (2008) U.S. patent 7,442,489
  6. ^ Shimizu, Akihiko; Itakura, Keisuke; Otsu, Takayuki; Imoto, Minoru (1969). "Monomer-isomerization polymerization. VI. Isomerizations of butene-2 with TiCl3 or Al(C2H5)3–TiCl3 catalyst". Journal of Polymer Science Part A: Polymer Chemistry. 7 (11): 3119. Bibcode:1969JPoSA...7.3119S. doi:10.1002/pol.1969.150071108.
  7. ^ a b c d Freeman, Andrew; Mantell, Susan C.; Davidson, Jane H. (2005). "Mechanical performance of polysulfone, polybutylene, and polyamide 6/6 in hot chlorinated water". Solar Energy. 79 (6): 624–37. Bibcode:2005SoEn...79..624F. doi:10.1016/j.solener.2005.07.003.
  8. ^ a b c d e Polybutylene Archived November 30, 2006, at the Wayback Machine
  9. ^ ISO 15876-1:2003 iso.org
  10. ^ T.E. Rolando (1998). Solvent-Free Adhesives. iSmithers Rapra. p. 35. ISBN 978-1-85957-133-0.
  11. ^ Doyle, Lucía (2022-03-20). "Extrusion foaming behavior of polybutene-1. Toward single-material multifunctional sandwich structures". Journal of Applied Polymer Science. 139 (12). doi:10.1002/app.51816. ISSN 0021-8995.
  12. ^ Doyle Gutierrez, Lucia (2022-12-02). A Circular Economy Approach to Multifunctional Sandwich Structures: Polymeric Foams for District Heating Pre-Insulated Pipes (Thesis thesis). HafenCity Universität Hamburg. doi:10.34712/142.35.
  13. ^ Hensler, Deborah R.; Pace, Nicholas M.; Dombey-Moore, Bonita; Giddens, Beth; Gross, Jennifer; Moller, Erik K. (2000). "Polybutylene Plumbing Pipes Litigation: Cox v. Shell Oil". In Hensler, Deborah R. (ed.). Class action dilemmas: pursuing public goals for private gain. Santa Monica, CA: RAND Institute for Civil Justice. pp. 375–98. ISBN 978-0-8330-2601-9.
  14. ^ Schneider, Martin (November 21, 1999). "Pipe problem getting fixed". The Baltimore Sun. Archived from the original on 2012-06-04. Retrieved 2010-07-29.
  15. ^ Vibien, P.; Couch, J.; Oliphant, K.; Zhou, W.; Zhang, B.; Chudnovsky, A. (2001). "Assessing material performance in chlorinated potable water applications" (PDF). Book Institute of Materials. 759: 863–72. ISSN 1366-5510. Archived from the original (PDF) on 2010-06-22. Retrieved 2010-07-30. also published as: Vibien, P.; Couch, J.; Oliphant, K.; Zhou, W.; Zhang, B.; Chudnovsky, A. (2001). "Chlorine resistance testing of cross-linked polyethylene piping materials". ANTEC 2001 Proceedings. Boca Raton: CRC Press. pp. 2833–9. ISBN 978-1-58716-098-1.
  16. ^ Pipe dream is nightmare for many, Miami Herald - September 12, 1993
  17. ^ "DuPont USA Settlement of the Canadian Class Action Lawsuits". Archived from the original on 2011-07-06. Retrieved 2010-10-01.
  18. ^ Polybutylene Plumbing Pipe Leak Relief
  19. ^ "Polybutylene (Poly-B) Pressure Water Piping" (PDF). municipalaffairs.alberta.ca. Government of Alberta. 2012-01-06. Retrieved 2019-09-09.
  20. ^ "Information for owners of new homes with polybutylene plumbing pipes" (PDF). commerce.wa.gov.au. March 21, 2023. Archived (PDF) from the original on 12 November 2023. Retrieved November 12, 2023.
  21. ^ Batajtis, Damian (27 March 2023). "Comprehensive Guide to polybutylene Piping Issues and Solutions in Australia". Wizard Leak Detection. Archived from the original on 12 November 2023. Retrieved November 12, 2023.
  22. ^ Cause of failure in polybutylene pipe & acetal fittings http://www.polybutylene.com/poly.html
  23. ^ "Polybutylene Piping". PropEx.com. Archived from the original on 2015-08-29. Retrieved 2015-07-17.

Further reading

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Polybutylene
Names
Other names
polybutene-1, poly(1-butene), PB-1
Identifiers
ChemSpider
  • none
ECHA InfoCard 100.111.056 Edit this at Wikidata
Properties
(C4H8)n
Density 0.95 g/cm3[1]
Melting point 135 °C (275 °F; 408 K)[1]
Related compounds
Related compounds
1-butene (monomer)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Polybutylene (polybutene-1, poly(1-butene), PB-1) is a polyolefin or saturated polymer with the chemical formula (CH2CH(Et))n. Not be confused with polybutene, PB-1 is mainly used in piping.[2]

Production

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Polybutylene is produced by polymerisation of 1-butene using supported Ziegler–Natta catalysts.

Catalysts

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Isotactic PB-1 is produced commercially using two types of heterogeneous Ziegler–Natta catalysts.[3] The first type of catalyst contains two components, a solid pre-catalyst, the δ-crystalline form of TiCl3, and solution of an organoaluminum cocatalyst, such as Al(C2H5)3. The second type of pre-catalyst is supported. The active ingredient in the catalyst is TiCl4 and the support is microcrystalline MgCl2. These catalysts also contain special modifiers, organic compounds belonging to the classes of esters or ethers. The pre-catalysts are activated by combinations of organoaluminum compounds and other types of organic or organometallic modifiers. Two most important technological advantages of the supported catalysts are high productivity and a high fraction of the crystalline isotactic polymer they produce at 70–80 °C under standard polymerization conditions.[4][5][6]

Characteristics

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PB-1 is a high molecular weight, linear, isotactic, and semi-crystalline polymer. PB-1 combines typical characteristics of conventional polyolefins with certain properties of technical polymers.

PB-1, when applied as a pure or reinforced resin, can replace materials like metal, rubber and engineering polymers. It is also used synergistically as a blend element to modify the characteristics of other polyolefins like polypropylene and polyethylene. Because of its specific properties it is mainly used in pressure piping, flexible packaging, water heaters, compounding and hot melt adhesives.

Heated up to 190 °C and above, PB-1 can easily be compression moulded, injection moulded, blown to hollow parts, extruded, and welded. It does not tend to crack due to stress.[dubiousdiscuss] Because of its crystalline structure and high molecular weight, PB-1 has good resistance to hydrostatic pressure, showing very low creep even at elevated temperatures.[7] It is flexible, resists impact well and has good elastic recovery.[3][8]

Isotactic polybutylene crystallizes in three different forms. Crystallization from solution yields form-III with the melting point of 106.5 °C. Cooling from the melt results in the form II which has melting point of 124 °C and density of 0.89 g/cm3. At room temperature, it spontaneously converts into the form-I with the melting point of 135 °C and density of 0.95 g/cm3.[1]

PB-1 generally resists chemicals such as detergents, oils, fats, acids, bases, alcohol, ketones, aliphatic hydrocarbons and hot polar solutions (including water).[3] It shows lower resistance to aromatic and chlorinated hydrocarbons as well as oxidising acids than other polymers such as polysulfone and polyamide 6/6.[7] Additional features include excellent wet abrasion resistance, easy melt flowability (shear thinning), and good dispersion of fillers. It is compatible with polypropylene, ethylene propylene rubbers, and thermoplastic elastomers.

Some properties:[7]

Application areas

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Piping systems

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The main use of PB-1 is in flexible pressure piping systems for hot and cold drinking water distribution, pre-insulated district heating networks and surface heating and cooling systems. ISO 15876 defines the performance requirements of PB-1 piping systems.[9] PB-1's most notable characteristics are weldability, temperature resistance, flexibility and high hydrostatic pressure resistance. The material can be classified PB 125 with a minimum required strength (MRS) of 12.5 MPa. Other features include low noise transmission, low linear thermal expansion, no corrosion and calcification.

PB-1 piping systems are no longer being sold in North America (see "Class action lawsuits and removal from building code approved usage", below). The overall market share in Europe and Asia is rather small but PB-1 piping systems have shown a steady growth in recent years. In certain domestic markets, e.g. Kuwait, the United Kingdom, Korea and Spain, PB-1 piping systems have a strong position.[8]

Plastic packaging

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Several PB-1 grades are commercially available for various applications and conversion technologies (blown film, cast film, extrusion coating). There are two main fields of application:

  • Peelable easy-to-open packaging where PB-1 is used as blend component predominantly in polyethylene to tailor peel strength and peel quality, mainly in alimentary consumer packaging and medical packaging.
  • Lowering seal initiation temperature (SIT) of high speed packaging polypropylene based films. Blending PB-1 into polypropylene, heat sealing temperatures as low as 65 °C can be achieved, maintaining a broad sealing window and good optical film properties.

Hot melt adhesives

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PB-1 is compatible with a wide range of tackifier resins. It offers high cohesive and adhesive strength and helps tailoring the "open time" of the adhesive (up to 30 minutes) because of its slow crystallisation kinetics. It improves the thermal stability and the viscosity of the adhesive.[10]

Compounding and masterbatches

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PB-1 accepts very high filler loadings in excess of 70%. In combination with its low melting point it can be employed in halogen-free flame retardant composites or as masterbatch carrier for thermo-sensitive pigments. PB-1 disperses easily in other polyolefins, and at low concentration, acts as processing aid reducing torque and/or increasing throughput.

Thermal insulation

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PB-1 can be foamed.[11] The use of PB-1 foam as thermal insulation is of great advantage for district heating pipes, since the number of materials in the sandwich structure is reduced to one, facilitating its recycling.[12]

Other applications

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Other applications include domestic water heaters, electrical insulation, compression packaging, wire and cable, shoe soles, and polyolefin modification (thermal bonding, enhancing softness and flexibility of rigid compounds, increasing temperature resistance and compression set of soft compounds).

Environmental longevity

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Plumbing and heating systems made from PB-1 have been used in Europe and Asia for more than 30 years. First reference projects in district heating and floor heating systems in Germany and Austria from the early 1970s are still in operation today.[8]

One example is the installation of PB-1 pipes in the Vienna Geothermal Project (1974) where aggressive geothermal water is distributed at a service temperature of 54 °C and 10 bar pressure. Other pipe materials in the same installation failed or corroded and had been replaced in the meantime.[8]

International standards set minimum performance requirements for pipes made from PB-1 used in hot water applications. Standardized extrapolation methods predict lifetimes in excess of 50 years at 70 °C and 10 bar.[8]

Class action lawsuits and removal from building code approved usage

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Polybutylene plumbing was used in several million homes built in the United States from around 1978 to 1997. Problems with leaks and broken pipes led to a class action lawsuit, Cox v. Shell Oil, that was settled for $1 billion.[13][14] The leaks were associated with degradation of polybutylene exposed to chlorinated water.[15]

Polybutylene water pipes are no longer accepted by the United States building codes and have been the subject[16] of class action lawsuits in both Canada and the U.S.[17][18] The National Plumbing Code of Canada 1995 listed polybutylene piping as acceptable for use with the exception of recirculation plumbing. The piping was removed from the acceptable for use list in the 2005 issue of the standard.[19]

In Australia in March 2023, the Department of Mines, Industry Regulation and Safety reported that Australian homes built in 2019-2020 that had used a certain brand of polybutylene piping, had become the subject of an enquiry due to the significance of water leaks reported.[20][21]

There is evidence to suggest that the presence of chlorine and chloramine compounds in municipal water (often deliberately added to retard bacterial growth) will cause deterioration of the internal chemical structure of polybutylene piping and the associated acetal fittings.[22] The reaction with chlorinated water appears to be greatly accelerated by tensile stress, and is most often observed in material under highest mechanical stress such as at fittings, sharp bends, and kinks. Localized stress whitening of the material generally accompanies and precedes decomposition of the polymer. In extreme cases, this stress-activated chemical "corrosion" can lead to perforation and leakage within a few years, but it also may not fail for decades. Fittings with a soft compression seal can give adequate service life.[further explanation needed]

Because the chemical reaction of the water with the pipe occurs inside the pipe, it is often difficult to assess the extent of deterioration. The problem can cause both slow leaks and pipe bursting without any previous warning indication. The only long-term solution is to completely replace the polybutylene plumbing throughout the entire building.[23]

See also

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References

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  1. ^ a b c Mark Alger, Mark S. M. Alger (1997). Polymer science dictionary. Springer. p. 398. ISBN 978-0-412-60870-4.
  2. ^ Whiteley, Kenneth S.; Heggs, T. Geoffrey; Koch, Hartmut; Mawer, Ralph L.; Immel, Wolfgang (2000). "Polyolefins". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a21_487. ISBN 978-3527306732.
  3. ^ a b c d Charles A. Harper (2006). Handbook of plastics technologies: the complete guide to properties and performance. McGraw-Hill Professional. p. 17. ISBN 978-0-07-146068-2.
  4. ^ Hwo, Charles C.; Watkins, Larry K. Laminated film with improved tear strength, European Patent Application EP0459742, Publication date 12/04/1991
  5. ^ Boo-Deuk Kim et al. (2008) U.S. patent 7,442,489
  6. ^ Shimizu, Akihiko; Itakura, Keisuke; Otsu, Takayuki; Imoto, Minoru (1969). "Monomer-isomerization polymerization. VI. Isomerizations of butene-2 with TiCl3 or Al(C2H5)3–TiCl3 catalyst". Journal of Polymer Science Part A: Polymer Chemistry. 7 (11): 3119. Bibcode:1969JPoSA...7.3119S. doi:10.1002/pol.1969.150071108.
  7. ^ a b c d Freeman, Andrew; Mantell, Susan C.; Davidson, Jane H. (2005). "Mechanical performance of polysulfone, polybutylene, and polyamide 6/6 in hot chlorinated water". Solar Energy. 79 (6): 624–37. Bibcode:2005SoEn...79..624F. doi:10.1016/j.solener.2005.07.003.
  8. ^ a b c d e Polybutylene Archived November 30, 2006, at the Wayback Machine
  9. ^ ISO 15876-1:2003 iso.org
  10. ^ T.E. Rolando (1998). Solvent-Free Adhesives. iSmithers Rapra. p. 35. ISBN 978-1-85957-133-0.
  11. ^ Doyle, Lucía (2022-03-20). "Extrusion foaming behavior of polybutene-1. Toward single-material multifunctional sandwich structures". Journal of Applied Polymer Science. 139 (12). doi:10.1002/app.51816. ISSN 0021-8995.
  12. ^ Doyle Gutierrez, Lucia (2022-12-02). A Circular Economy Approach to Multifunctional Sandwich Structures: Polymeric Foams for District Heating Pre-Insulated Pipes (Thesis thesis). HafenCity Universität Hamburg. doi:10.34712/142.35.
  13. ^ Hensler, Deborah R.; Pace, Nicholas M.; Dombey-Moore, Bonita; Giddens, Beth; Gross, Jennifer; Moller, Erik K. (2000). "Polybutylene Plumbing Pipes Litigation: Cox v. Shell Oil". In Hensler, Deborah R. (ed.). Class action dilemmas: pursuing public goals for private gain. Santa Monica, CA: RAND Institute for Civil Justice. pp. 375–98. ISBN 978-0-8330-2601-9.
  14. ^ Schneider, Martin (November 21, 1999). "Pipe problem getting fixed". The Baltimore Sun. Archived from the original on 2012-06-04. Retrieved 2010-07-29.
  15. ^ Vibien, P.; Couch, J.; Oliphant, K.; Zhou, W.; Zhang, B.; Chudnovsky, A. (2001). "Assessing material performance in chlorinated potable water applications" (PDF). Book Institute of Materials. 759: 863–72. ISSN 1366-5510. Archived from the original (PDF) on 2010-06-22. Retrieved 2010-07-30. also published as: Vibien, P.; Couch, J.; Oliphant, K.; Zhou, W.; Zhang, B.; Chudnovsky, A. (2001). "Chlorine resistance testing of cross-linked polyethylene piping materials". ANTEC 2001 Proceedings. Boca Raton: CRC Press. pp. 2833–9. ISBN 978-1-58716-098-1.
  16. ^ Pipe dream is nightmare for many, Miami Herald - September 12, 1993
  17. ^ "DuPont USA Settlement of the Canadian Class Action Lawsuits". Archived from the original on 2011-07-06. Retrieved 2010-10-01.
  18. ^ Polybutylene Plumbing Pipe Leak Relief
  19. ^ "Polybutylene (Poly-B) Pressure Water Piping" (PDF). municipalaffairs.alberta.ca. Government of Alberta. 2012-01-06. Retrieved 2019-09-09.
  20. ^ "Information for owners of new homes with polybutylene plumbing pipes" (PDF). commerce.wa.gov.au. March 21, 2023. Archived (PDF) from the original on 12 November 2023. Retrieved November 12, 2023.
  21. ^ Batajtis, Damian (27 March 2023). "Comprehensive Guide to polybutylene Piping Issues and Solutions in Australia". Wizard Leak Detection. Archived from the original on 12 November 2023. Retrieved November 12, 2023.
  22. ^ Cause of failure in polybutylene pipe & acetal fittings http://www.polybutylene.com/poly.html
  23. ^ "Polybutylene Piping". PropEx.com. Archived from the original on 2015-08-29. Retrieved 2015-07-17.

Further reading

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Frequently Asked Questions

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